Transient Absorption Spectrometer, also called Flash Photolysis Spectrometer is dedicated to measure transitions between quantum states in photo-excited sample. TA measurements are applicable to liquid and solid sample types.
The sample in the ground state is energized to an excited state with an intense laser pulse. The pulse may induce short lived intermediates such as electrons at higher energy levels, radicals or ions.
Process of deexcitation is monitored by measurement of the Transmittance/Absorbance of the white light beam going through the sample in case of a liquids and thin films or Reflectance of the sample in case of powders and non transparent bulk samples. The white light beam is produced by the Xenon Lamp.

System provides functionality that enables measurements of fluorescence and phosphorescence induced with the laser pulse.

With the Electrochemical extension, solid state samples submerged in electrolyte  can be investigated. When sample in contact with an electrolyte is examined, additional bias potential may be applied during the experiment. That gives one more control parameter and extends flexibility of the experiment.

If also the Analog Potentiostat is used, one can follow changes in current flowing between a sample and the electrolyte on the time scales of a single laser pulse!

Experimental procedures are fully automated.

Quantities measured by the instrument:

• Transmittance/Absorbance or Reflectance of the sample in nanosecond time scale,
• Laser-induced fluorescence spectrum,
• Life time of the photo-excited transients,
• Laser beam intensity on the input and the output of the sample chamber,
• I-V characteristics of the electrochemical samples (with Electrochemical extension).
• Electric current between the sample and electrolyte during laser pulse (with Analog Potentiostat)

1. Closed sample chamber.
2. Xenon Lamp with water cooling system and the Pulser.
3. Laser, typically Nd:YAG with possibility of choosing higher harmonics or even OPO.
4. Monochromator for UV, VIS and IR spectrum range.
5. Osciloscope.
6. Photomultiplier.
7. Timer synchronizing all the components of the system.
8. Potentiostat providing full characteristics of the electro-chemical sample.
9. Electro-chemical cuvette with platinum electrode and Ag/AgCl reference.

Sample chamber

Sample chamber screens the measurement setup from background diffused light and external electromagnetic fields.  It is equipped with a safety system that disconnects power supply of the Xenon Lamp and laser source after opening the chamber and system of easy and stable installation of several different experimental setups.

Inner measurement setups with different optical paths and sample cuvettes may be provided and adjusted to the individual experimental requirements.

Transient Absorption.

Laser-Induced Fluorescence.

Sample Chamber

• Safety system that disconnects the power supply of the Xenon Lamp and the Laser when the Sample Chamber is opened,
• Easy and stable installation of several different experimental setups with sample cuvettes,
• Two photodiodes: at the chamber entrance and output to measure laser pulse power,

Xenon Lamp

• 150 W xenon burner,
• Water cooling system,
• Low EM emission igniter,
• Light intensity stabilization mode that provides constant light power of the beam,
• Default beam diameter: 8 mm,
• Coupled with a Filter Wheel to modify the probing spectrum,

Xenon Lamp Pulser

• Pulse duration: 2 µs ÷ 2 ms,
• Pulse current: 8.5 ÷ 595 A.

Laser source

Quantel Q-Smart

• Laser type: Nd:YAG with 1064 nm base line,
• Up to four Harmonic Generation Modules: 213 nm, 266 nm, 355 nm, 532 nm,
• Beam diameter: 5 mm,
• Pulse duration: 5 ns,
• Beam power: 532 nm: 200 mJ, 350 nm: 100 mJ (10 Hz),

Any other laser type or OPO may be used at the sample chamber entrance.

Filter Wheels

• Up to 6 filters,
• Two edge (long pass) filters provided by default: 400 nm and 600 nm,
• Optional Air Mass Filter installed in the Filter Wheel coupled with the Xenon Lamp,

Photomultiplier

R928P Hammamatsu

• Anode to Cathode voltage range: 500 ÷ 1200 V,
• Spectral range: 160 ÷ 900 nm,